A new inorganic–organic hybrid [VO(pcp)], where pcp is the P,P0diphenylmethylenediphosphinate ligand, has been hydrothermally synthesized and structurally characterized. The X-ray analysis revealed an undulated 2D-layered structure, where VO5 moieties are connected through bridging phosphinate groups. Magnetic measurements in the range 300–2 K have shown a weak ferromagnetic interaction between vanadyl groups.
HYDROTHERMAL SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF A NEW 2D-LAYERED VANADIUM DIPHOSPHINATE: [VO(O2(C6H5)PCH2P(C6H5)O2)]
COSTANTINO, FERDINANDO;
2006
Abstract
A new inorganic–organic hybrid [VO(pcp)], where pcp is the P,P0diphenylmethylenediphosphinate ligand, has been hydrothermally synthesized and structurally characterized. The X-ray analysis revealed an undulated 2D-layered structure, where VO5 moieties are connected through bridging phosphinate groups. Magnetic measurements in the range 300–2 K have shown a weak ferromagnetic interaction between vanadyl groups.File in questo prodotto:
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