A new polymeric copper(II)-organic framework, [[Cu(4,40-bipy)(p(xyl)p)(H2O)2] 3 2(H2O)]n (1; p(xyl)p=P,P0-diphenylp- xylenediphosphinate, 4,40-bipy=4,40-bipyridine), has been synthesized. Single-crystal X-ray diffraction revealed that the structure of 1 consists of 2D grids connected by solvent water molecules. The temperature-dependent X-ray powder diffraction analysis of 1 has shown the formation of a dehydrated phase well modeled by a 3D structure with a binodal 4,6 connected topology.
Different structural networks determined by variation of the ligand skeleton in copper(II) diphosphinate coordination polymers
COSTANTINO, FERDINANDO;
2010
Abstract
A new polymeric copper(II)-organic framework, [[Cu(4,40-bipy)(p(xyl)p)(H2O)2] 3 2(H2O)]n (1; p(xyl)p=P,P0-diphenylp- xylenediphosphinate, 4,40-bipy=4,40-bipyridine), has been synthesized. Single-crystal X-ray diffraction revealed that the structure of 1 consists of 2D grids connected by solvent water molecules. The temperature-dependent X-ray powder diffraction analysis of 1 has shown the formation of a dehydrated phase well modeled by a 3D structure with a binodal 4,6 connected topology.File in questo prodotto:
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