A new regio- and stereospecific synthesis of a useful intermediate (7) for aphidicolane and stemodane diterpenoids is reported. The formation of ring C from 6b is achieved by Rh(II) catalyzed intramolecular carbon-hydrogen insertion
A ready synthesis of the ABC fragment releated to the stemodane and aphidicolane skeleton
CECCHERELLI, Paolo;CURINI, Massimo;MARCOTULLIO, Maria Carla;ROSATI, Ornelio
1993
Abstract
A new regio- and stereospecific synthesis of a useful intermediate (7) for aphidicolane and stemodane diterpenoids is reported. The formation of ring C from 6b is achieved by Rh(II) catalyzed intramolecular carbon-hydrogen insertionFile in questo prodotto:
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