The readily available and highly water-soluble [IrCl(Hedta)]Na complex was found to be an efficient and robust catalyst for water oxidation to molecular oxygen driven by the reduction of Ce+4 to Ce+3; its performances (TOF = 6.8 min-1 and TON > 12000), derived by UV-Vis spectroscopic, volumetric and electrochemical measurements, well compare with those of the best catalysts reported so far.
Iridium-EDTA as an Efficient and Readily Available Catalyst for Water Oxidation
SAVINI, ARIANNA;BELLACHIOMA, Gianfranco;ROCCHIGIANI, LUCA;ZUCCACCIA, Cristiano;MACCHIONI, Alceo
2012
Abstract
The readily available and highly water-soluble [IrCl(Hedta)]Na complex was found to be an efficient and robust catalyst for water oxidation to molecular oxygen driven by the reduction of Ce+4 to Ce+3; its performances (TOF = 6.8 min-1 and TON > 12000), derived by UV-Vis spectroscopic, volumetric and electrochemical measurements, well compare with those of the best catalysts reported so far.File in questo prodotto:
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