The presence of an azole group (pyrrole, indole, carbazole) in carbamate derivatives determines a remarkable increase in reactivity in basic hydrolysis: these compounds undergo hydrolysis up to 35,000 times faster than the corresponding methylamino derivatives. Mechanism and rationale for such behaviour are discussed.
Base-Catalyzed Hydrolysis of Carbamates. Remarkable Reactivity of Several Azole Derivatives
GERMANI, Raimondo;PIZZO, Ferdinando;SAVELLI, Gianfranco;
1991
Abstract
The presence of an azole group (pyrrole, indole, carbazole) in carbamate derivatives determines a remarkable increase in reactivity in basic hydrolysis: these compounds undergo hydrolysis up to 35,000 times faster than the corresponding methylamino derivatives. Mechanism and rationale for such behaviour are discussed.File in questo prodotto:
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