Oxidation of geraniol with monoperoxyphthalic acid in aqueous solutions of sodium hydrogen carbonate (pH = 8.3) and sodium hydroxide (pH = 12.5) gives regioselectively 6,7- and 2,3-epoxygeraniol in good and excellent yields, respectively.
pH-Controlled Regioselectivity of the Epoxidation of Geraniol in Water
FRINGUELLI, Francesco;GERMANI, Raimondo;PIZZO, Ferdinando
1991
Abstract
Oxidation of geraniol with monoperoxyphthalic acid in aqueous solutions of sodium hydrogen carbonate (pH = 8.3) and sodium hydroxide (pH = 12.5) gives regioselectively 6,7- and 2,3-epoxygeraniol in good and excellent yields, respectively.File in questo prodotto:
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