The oxidations of 18-methyl-19-nor-3~-isopimarol, 20-hydroxymanoyl oxide, 8,9-didehydro-7,8-dihydro-2/3- isopimarol, 26-isopimarol, 13-demethy1-13-deviny1-13-oxonezuko1, and 36-friedanol with lead tetraacetate and iodine have been investigated and the iodohydrin and tetrahydrofuran products are described. The nezukol and friedelin derivatives have yielded long-range oxidation products.
Iodohydrins and Tetrahydrofurans from Lead Tetraacetate-Iodine Oxidation of Terpenic Alcohols
CECCHERELLI, PaoloMembro del Collaboration Group
;CURINI, MassimoSupervision
;MARCOTULLIO, Maria CarlaInvestigation
;
1986
Abstract
The oxidations of 18-methyl-19-nor-3~-isopimarol, 20-hydroxymanoyl oxide, 8,9-didehydro-7,8-dihydro-2/3- isopimarol, 26-isopimarol, 13-demethy1-13-deviny1-13-oxonezuko1, and 36-friedanol with lead tetraacetate and iodine have been investigated and the iodohydrin and tetrahydrofuran products are described. The nezukol and friedelin derivatives have yielded long-range oxidation products.File in questo prodotto:
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