Cyperanes, eremophilanes and spirovetivanes have been prepared by acid catalyzed rearrangement of 3-keto-4,5-epoxy-eudesmanes. These transformations are of biogenetic significance and reinforce the hypothesis that the oxygenate eudesmanes are precursors of several sesquiterpene skeletons.
Biogenetic-Type Transformation of 3-Keto-4,5-Epoxy-Eudesmanes: Synthesis of Cyperanes, Eremophilanes and Spirovetivanes
CECCHERELLI, Paolo
Supervision
;CURINI, MassimoMembro del Collaboration Group
;MARCOTULLIO, Maria CarlaInvestigation
;ROSATI, OrnelioMembro del Collaboration Group
1989
Abstract
Cyperanes, eremophilanes and spirovetivanes have been prepared by acid catalyzed rearrangement of 3-keto-4,5-epoxy-eudesmanes. These transformations are of biogenetic significance and reinforce the hypothesis that the oxygenate eudesmanes are precursors of several sesquiterpene skeletons.File in questo prodotto:
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