A new synthesis of methylenomycin B, involving Rh(II)-catalyzed, intramolecular carbon-hydrogen insertion of diazoketone 2c, derived from 2,3-dimethyl-2-butenoic acid 2b, is reported.
A new synthetic route to Methylenomicyn B via Rhodium(II) mediated decomposition of alfa-beta-unsaturated alfa'-diazoketones
CECCHERELLI, Paolo;CURINI, Massimo;MARCOTULLIO, Maria Carla;ROSATI, Ornelio
1991
Abstract
A new synthesis of methylenomycin B, involving Rh(II)-catalyzed, intramolecular carbon-hydrogen insertion of diazoketone 2c, derived from 2,3-dimethyl-2-butenoic acid 2b, is reported.File in questo prodotto:
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