The synthesis of a new bench stable and odourless zinc thiolate is here reported. The thiolysis of epoxides effected using this reagent showed a considerable rate acceleration when effected in “on water” conditions. In addition the reactions evidenced a good regioselectivity combining the advantage of the procedures effected in organic solvent with those effected using Lewis acid’s catalysis.
"On water” thiolysis of epoxides promoted by PhSZnBr
BAGNOLI, Luana;MARINI, Francesca;TESTAFERRI, Lorenzo;SANTI, Claudio
2013
Abstract
The synthesis of a new bench stable and odourless zinc thiolate is here reported. The thiolysis of epoxides effected using this reagent showed a considerable rate acceleration when effected in “on water” conditions. In addition the reactions evidenced a good regioselectivity combining the advantage of the procedures effected in organic solvent with those effected using Lewis acid’s catalysis.File in questo prodotto:
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