The synthesis of 2-nitroalkanols from nitroalkanes and aldehydes occurs efficiently, in mild conditions without solvent, when mediated by layered Zr(KOPO3)2. The reaction has been tested in the preparation of ten different nitroalkanols and the data obtained seem to indicate that not only the surface but also the interlayer ≡P–O−K+ groups are involved in the catalytic process.
Potassium Exchanged Layered Zirconium Phosphate as Base Catalyst in the Synthesis of 2-Nitroalkanols
COSTANTINO, Umberto;CURINI, Massimo;MARMOTTINI, Fabio;ROSATI, Ornelio;
1994
Abstract
The synthesis of 2-nitroalkanols from nitroalkanes and aldehydes occurs efficiently, in mild conditions without solvent, when mediated by layered Zr(KOPO3)2. The reaction has been tested in the preparation of ten different nitroalkanols and the data obtained seem to indicate that not only the surface but also the interlayer ≡P–O−K+ groups are involved in the catalytic process.File in questo prodotto:
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