A charge-displacement analysis of gold–ethyne complexes shows the existence of a quantitative relationship between measurable properties and the chemical bond constituents in the Dewar–Chatt–Duncanson model. Through suitable experiments, these constituents may be disentangled and crucial insight into the nature of coordination bonds may thus be gained.
Disentanglement of donation and back-donation effects on experimental observables. A case study for gold-ethyne complexes
BISTONI, GIOVANNI;BELPASSI, LEONARDO;TARANTELLI, Francesco
2013
Abstract
A charge-displacement analysis of gold–ethyne complexes shows the existence of a quantitative relationship between measurable properties and the chemical bond constituents in the Dewar–Chatt–Duncanson model. Through suitable experiments, these constituents may be disentangled and crucial insight into the nature of coordination bonds may thus be gained.File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
