The first crystalline microporous zirconium phosphonate metal– organic framework (UPG-1) was synthesized using the novel tritopic ligand 2,4,6-tris(4-(phosphonomethyl)phenyl)-1,3,5-triazine. Its crystal structure was solved ab initio from laboratory powder X-ray diffraction data. UPG-1 displays remarkable thermal stability and hydrolysis resistance and has a good absorption affinity towards n-butane and CO2.
The first route to highly stable crystalline microporous zirconium phosphonate metal-organic frameworks.
TADDEI, MARCO;COSTANTINO, FERDINANDO;MARMOTTINI, Fabio;VIVANI, Riccardo
2014
Abstract
The first crystalline microporous zirconium phosphonate metal– organic framework (UPG-1) was synthesized using the novel tritopic ligand 2,4,6-tris(4-(phosphonomethyl)phenyl)-1,3,5-triazine. Its crystal structure was solved ab initio from laboratory powder X-ray diffraction data. UPG-1 displays remarkable thermal stability and hydrolysis resistance and has a good absorption affinity towards n-butane and CO2.File in questo prodotto:
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