A metastable copper(II) 3D hybrid with 4,40-bipyridine (4,40-bipy) and P,P0-diphenylethylenediphosphinate (pc2p2–) undergoes a spontaneous, quantitative, transformation to a stable 2D polymorphic species either spontaneously in water, or after thermal dehydration followed by hydration.
A Snapshot of a Coordination Polymer Self-Assembly Process: the Crystallization of a 3D Network Followed by the Spontaneous Transformation in Water to a 2D Pseudopolymorphic Phase
COSTANTINO, FERDINANDO;MARMOTTINI, Fabio;
2008
Abstract
A metastable copper(II) 3D hybrid with 4,40-bipyridine (4,40-bipy) and P,P0-diphenylethylenediphosphinate (pc2p2–) undergoes a spontaneous, quantitative, transformation to a stable 2D polymorphic species either spontaneously in water, or after thermal dehydration followed by hydration.File in questo prodotto:
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