Thin nanosheets from a layered zirconiumphosphate–carboxyphosphonate is reported here. Small Pd nanoparticles have been supported on these nanosheets by an efficient method. The resulting Pd-catalyst was fully characterized and tested in the Suzuki–Miyaura coupling. The catalytic system proved its efficiency as it was reused for several cycles and showed low Pd leaching.
Accessing stable zirconium carboxy-aminophosphonate nanosheets as support for highly active Pd nanoparticles
COSTANTINO, FERDINANDO;VIVANI, Riccardo;BASTIANINI, MARIA;PIERMATTI, Oriana;NOCCHETTI, Morena
;VACCARO, Luigi
2015
Abstract
Thin nanosheets from a layered zirconiumphosphate–carboxyphosphonate is reported here. Small Pd nanoparticles have been supported on these nanosheets by an efficient method. The resulting Pd-catalyst was fully characterized and tested in the Suzuki–Miyaura coupling. The catalytic system proved its efficiency as it was reused for several cycles and showed low Pd leaching.File in questo prodotto:
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