The potential of NMR spectroscopy to investigate inorganic systems assembled by, or whose reactivity is affected by, non-covalent interactions is described. Subjects that have received particular attention in recent years (halogen bonding and Frustrated Lewis Pairs) and more classical subjects that remain under- explored (self-aggregation of ion pairs in low polar solvents, behavior of MAO containing metallocenium ion pairs, and hydrogen bonding/ion pairing effects in Au(I) catalysis) are considered, using an innovative approach, always focusing on the crucial information that can be provided by NMR.

Disclosing the multi-faceted world of weakly interacting inorganic systems by means of NMR spectroscopy

ROCCHIGIANI, LUCA;MACCHIONI, Alceo
2016

Abstract

The potential of NMR spectroscopy to investigate inorganic systems assembled by, or whose reactivity is affected by, non-covalent interactions is described. Subjects that have received particular attention in recent years (halogen bonding and Frustrated Lewis Pairs) and more classical subjects that remain under- explored (self-aggregation of ion pairs in low polar solvents, behavior of MAO containing metallocenium ion pairs, and hydrogen bonding/ion pairing effects in Au(I) catalysis) are considered, using an innovative approach, always focusing on the crucial information that can be provided by NMR.
2016
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11391/1396018
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 20
  • ???jsp.display-item.citation.isi??? 20
social impact