A mild, practical, and simple procedure for phenyl selenoesters synthesis from several anhydrides and diphenyl diselenide was developed. This transition-metal-free method provides a straightforward entry to storable Fmocamino acid selenoesters which are effective chemoselective acylating reagents. An application to oligopeptide synthesis was illustrated.
General, Mild, and Metal-Free Synthesis of Phenyl Selenoesters from Anhydrides and Their Use in Peptide Synthesis
TEMPERINI, Andrea
;PIAZZOLLA, FRANCESCA;MINUTI, Lucio;CURINI, Massimo;
2017
Abstract
A mild, practical, and simple procedure for phenyl selenoesters synthesis from several anhydrides and diphenyl diselenide was developed. This transition-metal-free method provides a straightforward entry to storable Fmocamino acid selenoesters which are effective chemoselective acylating reagents. An application to oligopeptide synthesis was illustrated.File in questo prodotto:
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