Unprecedented hydrolysis reactions are observed in the gas phase in clusters containing doubly-charged vanadium oxides and hydroxides anions, SO2 and H2O. The experimental and computational study shows the cooperative effects of the vanadium species, V2O62- and HV3O92-, and sulfur dioxide in the enhancement of the hydrogen bonds of water that allows the acid-base reaction and the charge separation in the doubly-charged ion.
Sulphur dioxide cooperation in hydrolysis reactions of vanadium oxide and hydroxide cluster dianions
Rosi, Marzio;
2018
Abstract
Unprecedented hydrolysis reactions are observed in the gas phase in clusters containing doubly-charged vanadium oxides and hydroxides anions, SO2 and H2O. The experimental and computational study shows the cooperative effects of the vanadium species, V2O62- and HV3O92-, and sulfur dioxide in the enhancement of the hydrogen bonds of water that allows the acid-base reaction and the charge separation in the doubly-charged ion.File in questo prodotto:
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