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EnglishTransition metal-catalyzed C−H activation has emerged as an increasingly powerful strategy in molecular syntheses and a particularly attractive alternative to classical methods of cross-couplings. During the recent years, significant focus has been dedicated to further improve the sustainable nature of the C−H activation approach. As solvents represent a major portion of organic pollution caused by chemical syntheses, a range of nontoxic, biobased, sustainable solvents have been developed to substitute for common organic reaction media. In this review, we present a general perspective of biomass-derived solvents for transition metal-catalyzed C−H activation reactions and their unique potential for chemical syntheses up to January 2019.
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| Titolo: | Biomass-Derived Solvents for Sustainable Transition Metal-Catalyzed C-H Activation | |
| Autori: | ACKERMANN, LUTZ (Corresponding) | |
| Data di pubblicazione: | 2019 | |
| Rivista: | ||
| Abstract: | Transition metal-catalyzed C−H activation has emerged as an increasingly powerful strategy in mol...ecular syntheses and a particularly attractive alternative to classical methods of cross-couplings. During the recent years, significant focus has been dedicated to further improve the sustainable nature of the C−H activation approach. As solvents represent a major portion of organic pollution caused by chemical syntheses, a range of nontoxic, biobased, sustainable solvents have been developed to substitute for common organic reaction media. In this review, we present a general perspective of biomass-derived solvents for transition metal-catalyzed C−H activation reactions and their unique potential for chemical syntheses up to January 2019. | |
| Handle: | http://hdl.handle.net/11391/1454792 | |
| Appare nelle tipologie: | 1.1 Articolo in rivista |
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