Selective Au-C bond cleavage and arene-C-H activation in (C^N^C)Au(iii) pincer complexes are reversible, leading to a solvent-dependent proton shuttling process. The ether-free cleavage products are non-fluxional and show weak gold(iii)-arene interactions commensurate with intermediates postulated for CMD-type arene activation.

Arene C-H activation by gold(III): solvent-enabled proton shuttling, and observation of a pre-metallation Au-arene intermediate

Rocchigiani L.;
2017

Abstract

Selective Au-C bond cleavage and arene-C-H activation in (C^N^C)Au(iii) pincer complexes are reversible, leading to a solvent-dependent proton shuttling process. The ether-free cleavage products are non-fluxional and show weak gold(iii)-arene interactions commensurate with intermediates postulated for CMD-type arene activation.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11391/1534162
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