A new procedure for the regiospecific synthesis of 1-(phenylseleno)alkan-2-ones starting from (phenylseleno)acetic acid has been developed. When (phenylseleno)acetyl chloride, generated from the corresponding acid, was allowed to react with phenylthio(alkyl)cuprate(I) reagents, 1-(phenylseleno)alkan-2-ones were obtained in fair to good yields.[GRAPHICS].
(Phenylseleno)acetic acid based precursor for the regiospecific synthesis of 1-phenylseleno-2-alkanones
Temperini, A
;Ballarotto, M;
2022
Abstract
A new procedure for the regiospecific synthesis of 1-(phenylseleno)alkan-2-ones starting from (phenylseleno)acetic acid has been developed. When (phenylseleno)acetyl chloride, generated from the corresponding acid, was allowed to react with phenylthio(alkyl)cuprate(I) reagents, 1-(phenylseleno)alkan-2-ones were obtained in fair to good yields.[GRAPHICS].File in questo prodotto:
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