In this article we list the canonical hydrogenic Sturmian sets and the orthogonal transformations connecting them. The latter enjoy useful three-term recurrence relationships that allow their coefficient calculations even for large strings. The properties of elliptic hydrogenic Sturmians and their relations with canonical Sturmians are investigated. We derive three-term recursion relationships fulfilled by the coefficients of the transformation between elliptic Sturmians and canonical Sturmians. A discussion on the connections between configuration space and momentum space representations completes this article.
Hydrogenic orbitals in momentum space and hyperspherical harmonics. Elliptic sturmian basis sets.
AQUILANTI, Vincenzo;CAVALLI, Simonetta;
2003
Abstract
In this article we list the canonical hydrogenic Sturmian sets and the orthogonal transformations connecting them. The latter enjoy useful three-term recurrence relationships that allow their coefficient calculations even for large strings. The properties of elliptic hydrogenic Sturmians and their relations with canonical Sturmians are investigated. We derive three-term recursion relationships fulfilled by the coefficients of the transformation between elliptic Sturmians and canonical Sturmians. A discussion on the connections between configuration space and momentum space representations completes this article.File in questo prodotto:
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