In this article we list the canonical hydrogenic Sturmian sets and the orthogonal transformations connecting them. The latter enjoy useful three-term recurrence relationships that allow their coefficient calculations even for large strings. The properties of elliptic hydrogenic Sturmians and their relations with canonical Sturmians are investigated. We derive three-term recursion relationships fulfilled by the coefficients of the transformation between elliptic Sturmians and canonical Sturmians. A discussion on the connections between configuration space and momentum space representations completes this article.

Hydrogenic orbitals in momentum space and hyperspherical harmonics. Elliptic sturmian basis sets.

AQUILANTI, Vincenzo;CAVALLI, Simonetta;
2003

Abstract

In this article we list the canonical hydrogenic Sturmian sets and the orthogonal transformations connecting them. The latter enjoy useful three-term recurrence relationships that allow their coefficient calculations even for large strings. The properties of elliptic hydrogenic Sturmians and their relations with canonical Sturmians are investigated. We derive three-term recursion relationships fulfilled by the coefficients of the transformation between elliptic Sturmians and canonical Sturmians. A discussion on the connections between configuration space and momentum space representations completes this article.
2003
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11391/156653
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