The dynamics of the radical–radical reaction O(3P)+C3H5 has been investigated by means of the crossed molecular beam technique with mass spectrometric detection at a collision energy of 73.0 kJ mol1; the reaction mechanism of the H-displacement channel has been elucidated, while experimental evidence of the occurrence of one or more C–C bond-breaking channels at this collision energy has been obtained.
Crossed beam studies of radical-radical reactions: O(3P) + C3H5 (allyl)
LEONORI, FRANCESCA;BALUCANI, Nadia;CAPOZZA, Giovanni;SEGOLONI, ENRICO;CASAVECCHIA, Piergiorgio
2007
Abstract
The dynamics of the radical–radical reaction O(3P)+C3H5 has been investigated by means of the crossed molecular beam technique with mass spectrometric detection at a collision energy of 73.0 kJ mol1; the reaction mechanism of the H-displacement channel has been elucidated, while experimental evidence of the occurrence of one or more C–C bond-breaking channels at this collision energy has been obtained.File in questo prodotto:
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