Despite the technological importance of semiconductor black phosphorus (BP) in materials science, maintaining the stability of BP crystals in organic media and protecting them from environmental oxidation remains challenging. In this study, we present the synthesis of bulk BP and the exploitation of the viscoelastic properties of a regenerated silk fibroin (SF) film as a biocompatible substrate to transfer BP flakes, thereby preventing oxidation.
Mechanical Transfer of Black Phosphorus on a Silk Fibroin Substrate: A Viable Method for Photoresponsive and Printable Biomaterials
Martina Alunni CardinaliInvestigation
;Maria Rachele CeccariniInvestigation
;Silvia Bittolo BonInvestigation
;Tommaso RondiniMembro del Collaboration Group
;Silvia TacchiInvestigation
;Caterina PetrilloWriting – Review & Editing
;Tommaso BeccariWriting – Review & Editing
;Paola SassiWriting – Original Draft Preparation
;Luca Valentini
Conceptualization
2024
Abstract
Despite the technological importance of semiconductor black phosphorus (BP) in materials science, maintaining the stability of BP crystals in organic media and protecting them from environmental oxidation remains challenging. In this study, we present the synthesis of bulk BP and the exploitation of the viscoelastic properties of a regenerated silk fibroin (SF) film as a biocompatible substrate to transfer BP flakes, thereby preventing oxidation.File in questo prodotto:
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