In this paper we report the preparation, characterization, and evaluation of N-heterocyclic carbenes (NHC)-Ag(I) complexes as catalysts for the borono-Minisci reaction, a powerful and practical approach for the decoration of N-heterocycles. While it represents an unprecedented method, kinetic and cyclic voltammetric analyses evidenced how the complex structure influence the Ag(I)/Ag(II) redox potential and, in turn, the reaction efficiency and scope.
Investigating the Catalytic Efficiency of Supported NHC-Ag(I) Complexes in the Borono-Minisci Reaction
Giada Moroni;Alessandro Di Michele;Roccaldo Sardella;Antimo Gioiello
2024
Abstract
In this paper we report the preparation, characterization, and evaluation of N-heterocyclic carbenes (NHC)-Ag(I) complexes as catalysts for the borono-Minisci reaction, a powerful and practical approach for the decoration of N-heterocycles. While it represents an unprecedented method, kinetic and cyclic voltammetric analyses evidenced how the complex structure influence the Ag(I)/Ag(II) redox potential and, in turn, the reaction efficiency and scope.File in questo prodotto:
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