Steady-state and nanosecond laser flash photolysis measurements of 4-methoxybenzyl alcohol (1a), 4-methoxy-a-methylbenzyl alcohol (1b), 4,40-dimethoxydiphenylmethanol (1c) and 4-methoxy-a,a0-dimethylbenzyl alcohol (1d) were carried out in air-equilibrated CH2Cl2 and CH3CN solutions, in the presence of 9,10-dicyanoanthracene (DCA) and N-methylquinolinium tetrafluoroborate (NMQ+BF4 ) as sensitizers. In particular, steady-state irradiation with DCA produced carbonyl compounds and, with NMQ+BF4 , carbonyl compounds, ethers (substrates 1a–c) and styrene (substrate 1d) while time-resolved investigations gave evidence of charged species produced upon irradiation. The effect of solvent polarity on the reactivity was investigated; in the case of DCA, the reactivity increased with the solvent polarity, while the opposite was obtained when NMQ+BF4 was used. Quantum mechanical calculations at semiempirical (INDO/1-CI) and DFT (B3LYP/6-311G(d)) levels were used to support transient assignments and to obtain the charge and spin density distributions, respectively. The different photooxidation mechanisms operative with the neutral and charged sensitizer were rationalized in terms of the reactivity of free and complexed radical cations, respectively.
Anomalous Reactivity of Radical Cations Produced by Photosensitised Oxidation of 4-Methoxybenzyl Alcohol Derivatives: Role of the Sensitizer
DEL GIACCO, Tiziana;ELISEI, Fausto;
2008
Abstract
Steady-state and nanosecond laser flash photolysis measurements of 4-methoxybenzyl alcohol (1a), 4-methoxy-a-methylbenzyl alcohol (1b), 4,40-dimethoxydiphenylmethanol (1c) and 4-methoxy-a,a0-dimethylbenzyl alcohol (1d) were carried out in air-equilibrated CH2Cl2 and CH3CN solutions, in the presence of 9,10-dicyanoanthracene (DCA) and N-methylquinolinium tetrafluoroborate (NMQ+BF4 ) as sensitizers. In particular, steady-state irradiation with DCA produced carbonyl compounds and, with NMQ+BF4 , carbonyl compounds, ethers (substrates 1a–c) and styrene (substrate 1d) while time-resolved investigations gave evidence of charged species produced upon irradiation. The effect of solvent polarity on the reactivity was investigated; in the case of DCA, the reactivity increased with the solvent polarity, while the opposite was obtained when NMQ+BF4 was used. Quantum mechanical calculations at semiempirical (INDO/1-CI) and DFT (B3LYP/6-311G(d)) levels were used to support transient assignments and to obtain the charge and spin density distributions, respectively. The different photooxidation mechanisms operative with the neutral and charged sensitizer were rationalized in terms of the reactivity of free and complexed radical cations, respectively.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
