Volatile organic compounds emitted by materials used in museum display cases pose risks to the preser- vation of cultural heritage objects. Traditional assessment methods, such as the Oddy test, present limi- tations including subjectivity and lack of chemical specificity. To strengthen the Oddy test as a reference method for assessing emissions from display case materials, two complementary variants have been integrated: a cellulose-based modification, already employed to broaden the test’s sensitivity to the degradation of organic materials, and an IR-assisted approach, which enables the identification of corrosion products and thereby enhances both the interpretation of test re- sults and the overall assessment of materials. The multimodal Oddy test approach has been supported by chromatographic techniques (μCTE-TD-GC–MS and SPME-GC–MS) on a common set of showcase materi- als. This integrated methodology revealed differences in material emissions and identified compounds poten- tially harmful to metals and organic substrates. Our findings demonstrate the advantages of combining complementary analytical methods to enhance the evaluation of material suitability for museum environ- ments. This work supports the development of more robust, sensitive, and practical protocols for selecting safer materials, thereby contributing to improved preventive conservation strategies .
Enhancing the Oddy test for assessing the suitability of museums display cases materials: Insights from a comparative emission study
Barchi, Lucrezia;Romani, Aldo;
2026
Abstract
Volatile organic compounds emitted by materials used in museum display cases pose risks to the preser- vation of cultural heritage objects. Traditional assessment methods, such as the Oddy test, present limi- tations including subjectivity and lack of chemical specificity. To strengthen the Oddy test as a reference method for assessing emissions from display case materials, two complementary variants have been integrated: a cellulose-based modification, already employed to broaden the test’s sensitivity to the degradation of organic materials, and an IR-assisted approach, which enables the identification of corrosion products and thereby enhances both the interpretation of test re- sults and the overall assessment of materials. The multimodal Oddy test approach has been supported by chromatographic techniques (μCTE-TD-GC–MS and SPME-GC–MS) on a common set of showcase materi- als. This integrated methodology revealed differences in material emissions and identified compounds poten- tially harmful to metals and organic substrates. Our findings demonstrate the advantages of combining complementary analytical methods to enhance the evaluation of material suitability for museum environ- ments. This work supports the development of more robust, sensitive, and practical protocols for selecting safer materials, thereby contributing to improved preventive conservation strategies .I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.


