An ionic route to the CS2 degradation was studied by mass spectrometric and theoretical methods. Ionized mixtures containing carbon disulfide and ozone prove an effective source of S-2(+) and SO+ ions, formed by remarkable molecular reorganization and open to further reactions with ozone and surrounding species. Both the O-transfer and dissociative oxidation processes, typical of the 03 reactivity in ionized mixtures, were observed.
Ionization of carbon disulfide/ozone mixtures in atmospheric gases
ROSI, Marzio;
2005
Abstract
An ionic route to the CS2 degradation was studied by mass spectrometric and theoretical methods. Ionized mixtures containing carbon disulfide and ozone prove an effective source of S-2(+) and SO+ ions, formed by remarkable molecular reorganization and open to further reactions with ozone and surrounding species. Both the O-transfer and dissociative oxidation processes, typical of the 03 reactivity in ionized mixtures, were observed.File in questo prodotto:
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