We have reported that Amberlite IRA900F (Amb-F) is an efficient metal-free catalyst for the activation of Si-N and Si-O bonds and a mild base in a variety of organic transformations under solvent-free conditions, such as the addition of TMSN(3) to (E)-2-aryl-1-cyano-1-nitroethenes, nitriles, alpha,beta-unsaturated acids and their esters, and the addition of dimethylsilyl ketene acetal and ethyl nitroacetate to beta-nitro styrenes.
Amberlite IRA900F as a Solid Fluoride Source for a Variety of Organic Transformations under Solvent-Free Conditions
FRINGUELLI, Francesco;LANARI, DANIELA;PIZZO, Ferdinando;VACCARO, Luigi
2008
Abstract
We have reported that Amberlite IRA900F (Amb-F) is an efficient metal-free catalyst for the activation of Si-N and Si-O bonds and a mild base in a variety of organic transformations under solvent-free conditions, such as the addition of TMSN(3) to (E)-2-aryl-1-cyano-1-nitroethenes, nitriles, alpha,beta-unsaturated acids and their esters, and the addition of dimethylsilyl ketene acetal and ethyl nitroacetate to beta-nitro styrenes.File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
