Variously substituted aziridines were conveniently prepared by an aza-Michael Initiated Ring Closure (aza-MIRC) reaction starting from vinyl selenones and primary amines, aminoalcohols or diamines. The reactions proceed in very high yields at room temperature in toluene or water. A significant rate acceleration was observed under aqueous conditions.
One-pot synthesis of aziridines from vinyl selenones and variously functionalized primary amines
STERNATIVO, Silvia;MARINI, Francesca
;DEL VERME, FRANCESCA;TESTAFERRI, Lorenzo;TIECCO, Marcello
2010
Abstract
Variously substituted aziridines were conveniently prepared by an aza-Michael Initiated Ring Closure (aza-MIRC) reaction starting from vinyl selenones and primary amines, aminoalcohols or diamines. The reactions proceed in very high yields at room temperature in toluene or water. A significant rate acceleration was observed under aqueous conditions.File in questo prodotto:
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