In this communication we propose a convenient methodology to effect the oxidation of alkynes using ammonium persulfate and diphenyl diselenide as catalyst. The reactions effected in aqueous media lead to 1,2-unprotected dicarbonyl derivatives or to hemiacetals starting from terminal alkynes.
Oxidation of Alkynes in Aqueous Media Catalyzed by Diphenyl Diselenide
SANTORO, STEFANO;BATTISTELLI, BENEDETTA;TESTAFERRI, Lorenzo;TIECCO, Marcello;SANTI, Claudio
2010
Abstract
In this communication we propose a convenient methodology to effect the oxidation of alkynes using ammonium persulfate and diphenyl diselenide as catalyst. The reactions effected in aqueous media lead to 1,2-unprotected dicarbonyl derivatives or to hemiacetals starting from terminal alkynes.File in questo prodotto:
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