Crossed beam reactive scattering studies of the H displacement reaction of both ground 3P and excited 1D oxygen atoms with H2S show that the reaction dynamics changes dramatically upon electronic excitation: while the reaction of O(3P) is direct, that of O(1D) proceeds via a long‐lived complex.
EFFECT OF REAGENT ELECTRONIC EXCITATION ON THE DYNAMICS OF CHEMICAL REACTIONS: A HIGH RESOLUTION CROSSED BEAM STUDY OF O(3P,1D) + H2S
BALUCANI, Nadia;CASAVECCHIA, Piergiorgio;VOLPI, GIAN GUALBERTO
1991
Abstract
Crossed beam reactive scattering studies of the H displacement reaction of both ground 3P and excited 1D oxygen atoms with H2S show that the reaction dynamics changes dramatically upon electronic excitation: while the reaction of O(3P) is direct, that of O(1D) proceeds via a long‐lived complex.File in questo prodotto:
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