IRIS - Res&Arch Institutional Research Information System - Research & Archive
Anagrafe della Ricerca dell'Università degli Studi di Perugia.
EnglishWe show by extensive Green’s function calculations that the fingerprinting double peak observed in the title spectrum of the crystal is a pure nonatomic aggregation state effect, not to be seen in the gas phase spectrum. We clarify the mechanism for this effect as being due to the energy shift of hole-localized states induced by the crystal field and their strong mixing with close lying, otherwise Auger inactive, states. The generality of the phenomenon is discussed, identifying cases where it could be observed in the gas phase and not in the crystal.
Scheda prodotto non validato
Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo
| Titolo: | Aggregation state effect in Auger spectroscopy. The fluorine KLL spectrum of KF |
| Autori: | |
| Data di pubblicazione: | 1994 |
| Rivista: | |
| Abstract: | We show by extensive Green’s function calculations that the fingerprinting double peak observed in the title spectrum of the crystal is a pure nonatomic aggregation state effect, not to be seen in the gas phase spectrum. We clarify the mechanism for this effect as being due to the energy shift of hole-localized states induced by the crystal field and their strong mixing with close lying, otherwise Auger inactive, states. The generality of the phenomenon is discussed, identifying cases where it could be observed in the gas phase and not in the crystal. |
| Handle: | http://hdl.handle.net/11391/915728 |
| Appare nelle tipologie: | 1.1 Articolo in rivista |
File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
Copyright © 2020