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EnglishBy application of the Friedlander synthesis on 2,3-dihydro-l-benzothiepin-4(5H) one (4), the corresponding [4,5-b]quinoline derivatives 5a and 5b were obtained. Starting from the ketone (4) and by application of the Fischer indole synthesis, 1-benzolhiepino[4,5-b ]indole (6) and 1-benzothiepino[4,5-b]benzo[g]indole (7) were obtained. When β-naphthylhydrazine was used in the indolisation reaction, a mixture of 1-benzothiepino[4,5-b]benzo[e]indole (8) and 1-benzothiepino[4,3-b]benzo[e] indole (9) was obtained.
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| Titolo: | Indole and Quinoline Derivatives of 2,3-Dihydro-1-benzothiepin-4(5H)-one |
| Autori: | |
| Data di pubblicazione: | 1978 |
| Rivista: | |
| Abstract: | By application of the Friedlander synthesis on 2,3-dihydro-l-benzothiepin-4(5H) one (4), the corresponding [4,5-b]quinoline derivatives 5a and 5b were obtained. Starting from the ketone (4) and by application of the Fischer indole synthesis, 1-benzolhiepino[4,5-b ]indole (6) and 1-benzothiepino[4,5-b]benzo[g]indole (7) were obtained. When β-naphthylhydrazine was used in the indolisation reaction, a mixture of 1-benzothiepino[4,5-b]benzo[e]indole (8) and 1-benzothiepino[4,3-b]benzo[e] indole (9) was obtained. |
| Handle: | http://hdl.handle.net/11391/915741 |
| Appare nelle tipologie: | 1.1 Articolo in rivista |
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