Abstract A novel class of polystyrene-based gel-type resins (SPACeR, SP), containing the large 1, 4-bis (4-vinylphenoxy) benzene cross-linker, is introduced; SP-immobilized 1, 5, 7- triazabicyclo [4.4. 0] dec-5-ene (TBD) and triethylamine (TEA) bases are synthesized and characterized in terms of their structural, thermal and morphological features, and their catalytic efficiency in a series of fundamental chemical transformations under solvent-free conditions is investigated.
Novel cross-linked polystyrenes with large space network as tailor-made catalyst supports for sustainable media
MARROCCHI, Assunta;BARTOLLINI, ELENA;PETRUCCI, CHIARA;VACCARO, Luigi
2015
Abstract
Abstract A novel class of polystyrene-based gel-type resins (SPACeR, SP), containing the large 1, 4-bis (4-vinylphenoxy) benzene cross-linker, is introduced; SP-immobilized 1, 5, 7- triazabicyclo [4.4. 0] dec-5-ene (TBD) and triethylamine (TEA) bases are synthesized and characterized in terms of their structural, thermal and morphological features, and their catalytic efficiency in a series of fundamental chemical transformations under solvent-free conditions is investigated.File in questo prodotto:
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