The gas-phase reactivity of doubly-charged vanadium hydroxides anions with SO2 has been studied by experimental and computational methods. The obtained results highlight the role of sulfur dioxide in promoting unprecedented bond-forming reactions, which produce singly-charged products by breaking the VxOy skeleton or a terminal V−O bond.
Vanadium Hydroxide Cluster Ions in the Gas Phase: Bond-Forming Reactions of Doubly-Charged Negative Ions by SO2-Promoted V−O Activation
ROSI, Marzio;
2017
Abstract
The gas-phase reactivity of doubly-charged vanadium hydroxides anions with SO2 has been studied by experimental and computational methods. The obtained results highlight the role of sulfur dioxide in promoting unprecedented bond-forming reactions, which produce singly-charged products by breaking the VxOy skeleton or a terminal V−O bond.File in questo prodotto:
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