Molecular orientation is an important tool for the characterization of dynamical and kinetic properties in collisional processes. The Aquilanti mechanism concerns the role played by molecular orientation in collisions with chirality discrimination. Here, the Aquilanti mechanism is observed by calculations of stationary points and simulations based on first-principle molecular dynamics on prototypical bimolecular nucleophilic substitution (SN2) and bimolecular elimination mechanisms (E2).
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