Bio-based glycerol and aldehydes have been valorized by acetalization reaction over novel macroporous sulfonated polystyrene-type resins (MR-SP20-SO3H and MR-SP50-SO3H). The influence of reactants molar ratio, catalyst amount, temperature, and reaction time on the activity and selectivity to acetals have been investigated. Results showed that MR-SP20-SO3H and MR-SP50-SO3H confirm a high performance in the acetalization of the glycerol derivatives 1,2- propandiol, 1,3-propandiol, 3-methoxy-1,2-propandiol and monoacetin; these catalytic systems enable recover and reuse.

Glycerol valorization: Development of selective protocols for acetals production through tailor-made macroreticular acid resins

Marrocchi, Assunta;Trombettoni, Valeria;Campana, Filippo;Nazari, Alireza;Vaccaro, Luigi
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Abstract

Bio-based glycerol and aldehydes have been valorized by acetalization reaction over novel macroporous sulfonated polystyrene-type resins (MR-SP20-SO3H and MR-SP50-SO3H). The influence of reactants molar ratio, catalyst amount, temperature, and reaction time on the activity and selectivity to acetals have been investigated. Results showed that MR-SP20-SO3H and MR-SP50-SO3H confirm a high performance in the acetalization of the glycerol derivatives 1,2- propandiol, 1,3-propandiol, 3-methoxy-1,2-propandiol and monoacetin; these catalytic systems enable recover and reuse.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11391/1535294
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