The autoxidation of alkylbenzenes can be promoted photochemically in the presence of catalytic amounts of cerim (IV) ammonium nitrate (CAN) under very mild conditions, the efficiency of the process being significantly increased by added acids. It is suggested that the reaction is promoted by NO3, radicals formed in the light induced decomposition of CAN and that Ce(III) may be reoxidized to Ce(IV) by benzylperoxy radicals.

Cerium(IV) Ammonium Nitrate Catalyzed Photochemical Autoxidation of Alkylbenzenes

SEBASTIANI, Giovanni Vittorio;DEL GIACCO, Tiziana;ROL, Cesare
1985

Abstract

The autoxidation of alkylbenzenes can be promoted photochemically in the presence of catalytic amounts of cerim (IV) ammonium nitrate (CAN) under very mild conditions, the efficiency of the process being significantly increased by added acids. It is suggested that the reaction is promoted by NO3, radicals formed in the light induced decomposition of CAN and that Ce(III) may be reoxidized to Ce(IV) by benzylperoxy radicals.
1985
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11391/160543
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