New experimental trends of the non-coincidence effect (NCE) are evidenced in tert-butanol, in both symmetric OH and C-(CH3)(3) stretching bands. The positive NCE of the hydroxyl stretching band shows an interesting temperature effect different in the normal. and supercooled regions. The C-(CH3)(3) vibrational band has a negative NCE, similar to those of aromatic systems. Copyright (c) 2004 John Wiley N Sons, Ltd.
New evidence for non-coincidence effects in alcohols
MORRESI, Assunta;SASSI, Paola;PAOLANTONI, Marco;PALOMBO, FRANCESCA;
2005
Abstract
New experimental trends of the non-coincidence effect (NCE) are evidenced in tert-butanol, in both symmetric OH and C-(CH3)(3) stretching bands. The positive NCE of the hydroxyl stretching band shows an interesting temperature effect different in the normal. and supercooled regions. The C-(CH3)(3) vibrational band has a negative NCE, similar to those of aromatic systems. Copyright (c) 2004 John Wiley N Sons, Ltd.File in questo prodotto:
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