DDQ treatment of the Diels-Alder products 1 unexpectedly led to chloroderivatives 2. Chlorination did not occur during DDQ treatment of the fully aromatised compounds 3. These results point out that DDQ acted as an oxidant and source of chlorine. © 2004 Elsevier Ltd. All rights reserved.
Unexpected chlorination of angularly annelated [2.2]paracyclophanes during DDQ oxidation
MINUTI, Lucio;TATICCHI, Aldo;MARROCCHI, Assunta;LANARI, DANIELA;
2005
Abstract
DDQ treatment of the Diels-Alder products 1 unexpectedly led to chloroderivatives 2. Chlorination did not occur during DDQ treatment of the fully aromatised compounds 3. These results point out that DDQ acted as an oxidant and source of chlorine. © 2004 Elsevier Ltd. All rights reserved.File in questo prodotto:
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