In the search for molecules for organic photonics and electronics, several strategies have been used to modulate physical and chemical properties of [2.2]paracyclophane derivatives by sequential functionalization of their three-dimensional cores. This review summarizes the major design and synthetic strategies for tuning paracyclophane-containing small molecules by introducing various moieties featuring (hetero)aromatic rings directly connected to each other, as well as alternating (hetero)aryl and ethylene or ethynylene units. Several examples are presented that elucidate the structural, optical, and electronic consequences of incorporating these fragments in the aromatic decks, particularly relating to applications in organic optoelectronics

Organic Small-Molecules for Photonics and Electronics from the [2.2]Paracyclophane Scaffold

MARROCCHI, Assunta;VACCARO, Luigi
2012

Abstract

In the search for molecules for organic photonics and electronics, several strategies have been used to modulate physical and chemical properties of [2.2]paracyclophane derivatives by sequential functionalization of their three-dimensional cores. This review summarizes the major design and synthetic strategies for tuning paracyclophane-containing small molecules by introducing various moieties featuring (hetero)aromatic rings directly connected to each other, as well as alternating (hetero)aryl and ethylene or ethynylene units. Several examples are presented that elucidate the structural, optical, and electronic consequences of incorporating these fragments in the aromatic decks, particularly relating to applications in organic optoelectronics
2012
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11391/920583
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